I wold say a. 120°.
Considering the vector diagram: You can see that the resultant ##vecR## is perpendicular to the smaller vector ##vecA##. The angle ##alpha## can be found from trigonometry considering the triangle of hypotenuse ##2## and opposite side ##1## and get: ##1=2sin(alpha)## so that ##sin(alpha)=1/2## and ##alpha=30°## giving a total angle of: ##90°+30°=120°##



